Deuterium
D2
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General Characteristics Health Hazards Material Recommendations
A colorless, flammable and odorless gas. A Simple asphyxiant Normal materials can be used.
TLV-TWA Flammable Limits DOT Class / Label
None Established 5 - 75% 2.1/ Flammable Gas
Molecular Weight Specific Gravity Specific Volume
4.0 0.139 @ 70 F 96.0 cu.ft./lb @ 70 F
CGA Valve Outlet CAS Registry No. UN Number
350 7782-39-0 11957
National Stock Number (NSN) Applicable to Deuterium MIL Specs/ Fed Specs
MSDS for Deuterium


Grade
Part #
Purity Minimum Cylinder
Size
Volume
Liters
Pressure
@ 70 F
Comments
Ultra High
469300
99.8% Min.
LBS

50

1740

None

Chemically Pure
469400
99.5% Min.
044
016
007
LBS
5000
1800
840
50
1850
2000
2000
1740

Uses: Deuterium is used in tracer applications, in reaction rate studies, and exchange reaction studies, i.e., reactions in which one or more deuterium atoms trade places with light hydrogen atoms in some ion or molecule.

General

(D, or 2H), also called HEAVY HYDROGEN, isotope of hydrogen with atomic weight of approximately 2. Its nucleus, consisting of one proton and one neutron, has double the mass of the nucleus of ordinary hydrogen. Deuterium is a stable atomic species found in natural hydrogen compounds to the extent of 0.014 to 0.015 percent.

Deuterium was discovered (1931) by the American chemist Harold C. Urey (for which he was awarded the Nobel Prize for Chemistry in 1934) and his associates F.G. Brickwedde and G.M. Murphy. Urey predicted a difference between the vapour pressures of molecular hydrogen (H2) and of a corresponding molecule with one hydrogen atom replaced by deuterium (HD) and, thus, the possibility of separating these substances by distillation of liquid hydrogen. The deuterium was detected (by its atomic spectrum) in the residue of a distillation of liquid hydrogen. Deuterium was first prepared in pure form in 1933 by G.N. Lewis, using the electrolytic method of concentration discovered by E.W. Washburn. When water is electrolyzed--i.e., decomposed by an electric current (actually a water solution of an electrolyte, usually sodium hydroxide, is used)- the hydrogen gas produced contains a smaller fraction of deuterium than the remaining water, and, hence, deuterium is concentrated in the water. Very nearly pure deuterium oxide (D2O; heavy water) is secured when the amount of water has been reduced to about one hundred-thousandth of its original volume by continued electrolysis. This was the standard method of preparation of
D2O before World War II.

Deuterium enters into all chemical reactions characteristic of ordinary hydrogen, forming equivalent compounds. Deuterium, however, reacts more slowly than ordinary hydrogen, a criterion that distinguishes the two forms of hydrogen. Because of this property, among others, deuterium is extensively used as an isotopic tracer in investigations of chemical and biochemical
reactions involving hydrogen.

The nuclear fusion of deuterium atoms or of deuterium and the heavier hydrogen isotope, tritium, at high temperature is accompanied by release of an enormous amount of energy; such reactions have been used in thermonuclear weapons. Since 1953, the stable solid substance lithium deuteride (LiD) has been used in place of both deuterium and tritium.

The physical properties of the molecular form of the isotope deuterium (D2) and the molecules of hydrogen deuteride (HD) are compared with those of the molecules of ordinary hydrogen (H2) in the Table.

Last Updated: 98 AUG 01